File:Deltahedral-borane-cluster-array-numbered-3D-bs-17.png

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Summary

Description

Ball-and-stick models showing structures of the boron skeletons of borane clusters. The numbering indicates the number of vertices in each closo cluster. The nido and arachno clusters derived from each closo cluster are shown alongside.

For an explanation of the concepts, see polyhedral skeletal electron pair theory.

For context, see Alan J. Welch, "The significance and impact of Wade’s rules", Chem. Commun. (2013) 49, 3615-3616.

The diagram is based on the following crystal structures:

4. J. Chem. Phys. (1953) 21, 172-172 (CSD 1603048, ICSD 27872)

5. Eur. J. Inorg. Chem. (2002) 1293-1300 (CSD MOFLEY)

6. Phys. Rev. B (2006) 74, 075110 (see also CSD 1651993)

7. Inorg. Chem. (2011) 50, 2580-2589 (CSD IYAHUM)

8. Inorg. Chem. (1969) 8, 2771-2774 (CSD FUZCUY)

9. Z. Anorg. Allg. Chem. (1999) 625, 1059-1072 (CSD GOXWUL)

10. Koord. Khim. (1992) 18, 387 (WAKXIP)

11. Z. Anorg. Allg. Chem. (1999) 625, 1193-1200 (CSD LOSDIG)

12. Z. anorg. allg. Chem. (2000) 626, 323–325 (CSD 1651993, ICSD 92501)

Colour code:

Boron, B: pink

Model manipulated in Avogadro 1.2 and image generated in CCDC Mercury 3.8.

Date

11 April 2021

Source

Own work

Author

Ben Mills

Permission
(Reusing this file)

This work has been released into the public domain by its author, Benjah-bmm27. This applies worldwide.

In some countries this may not be legally possible; if so:
Benjah-bmm27 grants anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law.

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	Date/Time	Thumbnail	Dimensions	User	Comment
current	19:40, 11 April 2021		3,478 × 7,958 (4.45 MB)	Benjah-bmm27	== {{int:filedesc}} == {{Information \| Description = Ball-and-stick models showing structures of the boron skeletons of borane clusters. The numbering indicates the number of vertices in each ''closo'' cluster. The ''nido'' and ''arachno'' clusters derived from each ''closo'' cluster are shown alongside. For an explanation of the concepts, see [[:en:Polyhedral skeletal electron pair theory\|polyhedral skeletal electr...

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Horizontal resolution	72 dpi
Vertical resolution	72 dpi
Color space	sRGB
Image width	3,478 px
Image height	7,958 px
Software used	Adobe Photoshop Elements 14.0 (Macintosh)
Date and time of digitizing	20:23, 11 April 2021
Date metadata was last modified	21:03, 11 April 2021
File change date and time	21:03, 11 April 2021
Unique ID of original document	xmp.did:a6a90d30-9a98-48af-8040-36f25be12d07

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File:Deltahedral-borane-cluster-array-numbered-3D-bs-17.png

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